The influence of PMS and PDS oxidants on reaction rate of photocatalytic degradation of p-cresol over TiO2 powder - Advanced Oxidation Process

Authors

  • M. Surendra Varma
  • S. Suresh

Keywords:

Photodegradation, p-cresol, PMS, PDS, TiO2 Catalyst.

Abstract

The degradation of p-cresol is approved out under UV-visible light by TiO2 as a photocatalyst. In the direction of determining the efficiency of the photocatalyst, the, unlike variables, studied built-in the amount of photocatalyst, consequence of oxidants peroxomonosulphate (PMS) and peroxodisulphate (PDS) on the photocatalytic oxidation of p-cresol on elucidation TiO2 surface have been investigating. The efficiencies of these oxidants on photocatalytic degradation of p-cresol are compared with that of PMS and PDS.The investigational results indicate that these oxidants reveal improved rates of mineralization of p-cresol. A response mechanism, linking the production of hydroxyl radicals and sulfate radicals. In conclusion, this investigation indicated a high potential of TiO2 suspension to remove the high-level concentration of p-cresol under UV radiation.

References

Peiró, A.M.; Ayllón, J.A.; Peral, J.; Doménech, X. TiO2-photocatalyzed degradation of phenol and ortho-substituted phenolic compounds. Appl. Catal. B: Environ. 2001, 30, 359–373.

Rathi, A.; Rajor, H.K.; Sharma, R.K. Photodegradation of direct yellow-12 using UV/H2O2/Fe2+. J. Hazard. Mater. 2003, 102, 231–241.

Schmelling, D.C.; Gray, K.A. Photocatalytic transformation and mineralization of 2, 4, 6- trinitrotoluene (TNT) in TiO2 slurries. Water Res. 1995, 29, 2651–2662.

Glaze, W. Drinking-water treatment with ozone. Environ. Sci. Technol. 1987, 21, 224–230.

Litter, M.I. Heterogeneous photocatalysis: Transition metal ions in photocatalytic systems. Appl.Catal. B: Environ. 1999, 23, 89–114.

Brezova, V.; Stasko, A. Spin trap study of hydroxyl radicals formed in the photocatalytic system TiO2-water-p-cresol-oxygen. J. Catal. 1994, 147, 156–162.

Pardeshi, S.K.; Patil, A.B. A simple route for photocatalytic degradation of phenol in aqueous zinc oxide suspension using solar energy. Solar Energ. 2008, 82, 700–705.

Chen, C.C.; Lu, C.S.; Chung, Y.C. Photocatalytic degradation of ethyl violet in aqueous solution mediated by TiO2 suspensions. J. Photochem. Photobiol. A: Chem. 2006, 181, 120–125.

Kandavelu, V.; Kastien, H.; Thampi, K.R. Photocatalytic degradation of isothiazolin-3- ones in water and emulsion paints containing nanocrystalline TiO2 and ZnO catalysts. Appl.Catal. B: Environ. 2004, 48, 101–111.

Lachheb, H.; Puzenat, E.; Houas, A.; Ksibi, M.; Elaloui, E.; Guillard, C.; Herrmann, J.M. Photocatalytic degradation of various types of dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in water by UV-irradiated titania. Appl. Catal. B: Environ. 2002, 39, 75–90.

Mai, F.; Chen, C.; Chen, J.; Liu, S. Photodegradation of methyl green using visible irradiation in ZnO suspensions: Determination of the reaction pathway and identification of intermediates by a high-performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry method. J. Chromatogr. A 2008, 1189, 355–365.

Özgür, Ü.; Alivov, Y.; Liu, C.; Teke, A.; Reshchikov, M.; Do an, S.; Avrutin, V.; Cho, S.; Morkoc, H. A comprehensive review of ZnO materials and devices. J. Appl.Phys. 2005, 98, 041301.

Akyol, A.; Bayramoglu, M. Photocatalytic degradation of Remazol Red F3B using ZnO catalyst. J. Hazard. Mater. 2005, 124, 241–246.

Akyol, A.; Yatmaz, H.C.; Bayramoglu, M. Photocatalytic decolorization of Remazol Red RR in aqueous ZnO suspensions. Appl. Catal. B: Environ. 2004, 54, 19–24.

da Silva, C.G.; Faria, J.L. Photochemical and photocatalytic degradation of an azo dye in aqueous solution by UV irradiation. J. Photochem. Photobiol. A: Chem. 2003, 155, 133–143.

Guillard, C.; Disdier, J.; Herrmann, J.M.; Lehaut, C.; Chopin, T.; Malato, S.; Blanco, J., Comparison of various titania samples of industrial origin in the solar photocatalytic detoxification of water containing 4-chlorophenol. Catal. Today 1999, 54, 217–228.

Height, M.; Pratsinis, S.; Mekasuwandumrong, O.; Praserthdam, P. Ag-ZnO catalysts for UVphotodegradation of methylene blue. Appl. Catal. B: Environ. 2006, 63, 305–312.

Konstantinou, I.K.; Albanis, T.A. TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review. Appl. Catal. B: Environ. 2004, 49, 1–14.

Mehrotra, K.; Yablonsky, G.S.; Ajay, K. Kinetic studies of photocatalytic degradation in a TiO2 slurry system: Distinguishing working regimes and determining rate dependences. Ind. Eng. Chem. Res. 2003, 42, 2273–2281.

Callahan, M.; Slimak, M.; Gabel, N.; May, I.; Fowler, C.; Freed, J.R.; Jennings, P.; Dupree, R. Water-Related Environmental Fate of 129 Priority Pollutants. Volume 1: Introduction and technical background, metals and inorganics, pesticides and PCBs; Final Report 069443; U.S. Environmental Protection Agency: Washington, DC, USA, 1979.

Cooper, E. On the Relations of Phenol and Meta-Cresol to Proteins; A Contribution to our knowledge of the Mechanism of Disinfection. Biochem. J. 1912, 6, 362–387.

Kavitha, V.; Palanivelu, K. Destruction of cresols by Fenton oxidation process. Water Res. 2005, 39, 3062–3072.

Flox, C.; Cabot, P.-L.; Centellas, F.; Garrido, J.A.; Rodríguez, R.M.; Arias, C.; Brillas, E. Solar photoelectro-Fenton degradation of cresols using a flow reactor with a boron-doped diamond anode. Appl. Catal. B: Environ. 2007, 75, 17–28.

Guyer, H. Industrial Processes and Waste Stream Management; John Wiley & Sons Inc: New York, NY, USA, 1998.

Abdollahi, Y.; Abdullah, A.H.; Zainal, Z.; Yusof, N.A. Photodegradation of m-cresol by Zinc Oxide under Visible-light Irradiation. Int. J. Chem. 2011, 3, 31–43.

Abdollahi, Y.; Abdullah, A.H.; Zainal, Z.; Yusof, N.A. Photodegradation of o-cresol by ZnO under UV irradiation. J. Am. Sci. 2011, 7, 165–170.

Martin R.W., Plastic Laboratory Electric Company, Pittsfield, mass.

Dhanalakshmi K.B, Anandan S, Madhavan J, Maruthamuthu P., Solar energy material and solar cells, 92 (2008) 457-463.

National Pollutant Inventory: Department of the environment, water, heritage and the arts, Australia. [http://www.npi.gov.au/resource/chlorophenols-di-tri-tetra]

Muller F, Caillard L: Chlorophenols. In Ullmann’s Encyclopedia of Industrial Chemistry. John Wiley & Sons, Inc; 2011. DOI: 10.1002/14356007.a07_001. pub2.

Luukkonen V., Determination of chlorophenols from water by solid phase micro- extraction ion mobility spectrometry (SPME-IMS), Master Thesis, Lappeenranta University of Technology (2013)

Oswald I.D, Allan D.R, Motherwell W.S and Parsons S., Structure of the monofluoro and monochlorophenols at low temperature and high pressure, Acta Crystallographica section B: Structural science, 61.1 (2005) 69-79.

Turves I, Rodriguez I, Garcia C.M and Cela R., Determination of chlorophenols in drinking water with high resolution gas chromatography tandem mass spectrometry, journal of chromatography A743.2 (1996) 283-292.

Garny V., Euro chlor risk Assessment for the marine environment, Modern chlor-alkali technology 8 (2008) 44.

https://www.drugfuture.com/chemdata/chlorophenols.html. (Accessed Jun. 2015).

Dindar, B. & Içli, S., Journal of Photochemistry and Photobiology A: Chemistry, 140(3)

(2001) 263-268.

Hashimoto K, Kawai T and Sakata T., J. Phys. Chem., 88 (1984)4083.

Vaino V. Sacco O, Sannino D., Electric energy saving in photocatalytic removal of crystal violet dye through the simultaneous use of long persistent blue phosphores, nitrogen-doped TiO2 and UV-light emitting diodes, Journal clean prod, 210 (2019) 1015- 1021.

Vaiano V, Sacco O, Matarangolo M., Photocatalytic degradation of Paracetamol under UV irradiation using TiO2 – graphite composites, Catalysis today, 515 (2018) 230-236.

Torres-Pinto A. Sampaio M, Silva G, Faria J, Silva M., Recent strategies for hydrogen peroxide production by metal-free carbon nitride photocatalysts, catalysts (2019) https://doi.org/10.3390/cata19120990.

Sun Q, Zhang T, Wang F, Liu C, Wu C, Xie R, Zheng Y., Ultraviolet photosensitized transformation mechanism of microcystin-LR by natural organic matter in raw water, Chemosphere, 209 (2018) 96–103.

Ran Z, Fang Y, Sun J, Ma C and Li S., Photocatalytic oxidative degradation of carbamazepine by TiO2 irradiated by UV light emitting diode , Catalysts, 10(5) (2020) 540. https://doi.org/10.3390/catal10050549.

Ran Z, Wang L, Fang Y, Ma C, Li S., Photocatalytic degradation of atenolol by TiO2 irradiated with an ultraviolet light emitting diode. Catalysts, 876: (2019)1–17.

Oulopoulos S, Yerkinova A, Ulykbanova G, Inglezakis V., Photocatalytic treatment of organic pollutants in a synthetic wastewater using UV light and combinations of TiO2, H2O2 and Fe(III) (2019)., https://doi.org/10.1371/journal.pone.0216745.

Perović K, dela Rosa FM, Kovačić M, Kušić H, Lavrenčić Štangar U, Fresno F, Dionysiou DD, Loncaric Bozic A., Recent achievements in development of TiO2-based composite photocatalytic materials for solar driven water purification and water splitting., Materials (2020). https://doi.org/10.3390/ma13061338.

Onkani S, Diagboya P, Mtunzi F, Klink M, Olu-Owolabi B, Pakade V., Comparative study of the photocatalytic degradation of 2 – chlorophenol under UV irradiation using pristine and Ag-doped species of TiO2, ZnO and ZnS photocatalysts. J Environ Manag 2 (2020) 60:110145. https://doi.org/10.1016/j.jenvman.2020.110145.

Mortazavian S, Saber A, James D., Optimization of photocatalytic degradation of acid blue 113 and acid red 88 textile dyes in a UV-C/TiO2 suspension system: application of response surface methodology (rsm). Catalysts (2019)

. https://doi.org/10.3390/catal9040360.

Liang R, Van Leuwena J, Bragg L, Arlos M, Fonga L, Schneider O, Jaciw-Zurakowsky I, Fattahi A, Rathoda S, Peng P, Servos M, Zhou Y., Utilizing UV-LED pulse width modulation on TiO2 advanced oxidation processes to enhance the decomposition efficiency of pharmaceutical micropollutants. Chem Eng J 361: (2019) 439–449.

Keshavarzfathy M, Taghipour F., Radiation modeling of ultraviolet light-emitting diode (UV-LED) for water treatment. J Photochem Photobiol A 377: (2019) 58–66.

Kanmani K, Sundar K., Progression of photocatalytic reactors and its comparison: a review, Chem Eng Res Des. 154: (2019)135–150.

Gao Z, Lin Y, Xu B, Xi Y, Hu C, Cao T, Zou X and Gao N., Evaluating iopamidol degradation performance and potential dual wavelength synergy by UV-LED irradiation and UV-LED/chlorine treatment, Chem Eng J, 360 (2019) 806-816.

Nasir Shehzad, Muhammad Zafer, Muhammad Ashfaq, Abdul Razzaq, Parveen Akhter, Nabeel Ahmad, Ainy Hafeez, Kshaf Azam, Murid Hussain and Woo Young Kim., Development of AgFeO2/rGO/TiO2 Ternary Composite photocatalysts for enhanced photocatalytic dye decolorization, Crystals, 10 (2020) 923.

Willian H.Ferreira, Leonardo G.A.Silva, Barbara C.S.Pereira, Rodrigo F.Gouvêa, Cristina T.Andrade., Adsorption and visible-light photocatalytic performance of a graphene derivative for methylene blue degradation Environmental Nanotechnology, Monitoring & Management, Volume 14, December 2020, 100373.

Annika Holm, Marwa Hamandi, Karima Sahel, Frederic Dappozze and Chantal Guillard., Impact of H2O2 on the actic and formic acid degradation in presence of TiO2 rutile and Anatase phases under UV and Visible light, Catalysts, 10 (2020) 1131. Doi:10.3390/catall0101131.

Glenson R. Panghulan, Magdaleno R. Vasquez Jr, Yasmin D. Edanol, Narong Chanlek and Leon M. Payawan Jr., Synthesis of TiN/N-doped TiO2 composite films as visible light active photocatalyst, ournal of vaccum science and Technology B38, 062203 (2020).

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Published

2023-09-30

How to Cite

Varma, M. S. ., & Suresh, S. . (2023). The influence of PMS and PDS oxidants on reaction rate of photocatalytic degradation of p-cresol over TiO2 powder - Advanced Oxidation Process. The Journal of Contemporary Issues in Business and Government, 29(3), 287–298. Retrieved from https://cibgp.com/au/index.php/1323-6903/article/view/2598